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I was pleased with my first try at pouring an acrylic skin; the colors were beautiful. There was only one hitch, I couldn't peel it off the plastic backing I was using (next time, butcher paper). Not to be deterred, I used the paint with the plastic backing it was dragging along and put a section of it inside a large PMC pendant I had made - based on a template from Gordon Uyehara's useful book, Metal Clay Fusion. (Photo on upper right.)
Eureka, it looks like enamel! I used another bit with a smaller pendant, and it took like a champ to being riveted as part of an acrylic sandwich between two pieces of metal clay (photo on right below). I'm hooked. I see many more and varied acrylic skins in my future, to use not only with jewelry but also with my mixed media pieces. Stay tuned.